Release to the environment of this substance can occur from industrial use: manufacturing of the substance. This section provides links to the list of precautions (precautionary statements) and to the guidance on safe use, if they have been provided in REACH registration dossiers. No smoking. cooling liquids in refrigerators, oil-based electric heaters). Labelling acc. If the substance is covered by more than one CLH entry (e.g. The CLP Regulation ensures that the hazards presented by chemicals are clearly communicated to workers and consumers in the European Union through classification and labelling of chemicals. Please upgrade your Internet Explorer to a newer version. Hazard Statements: ... Ethanol 64-17-5 200-578-6 95 -98 Natural Gasoline 68425-31-0 232-349 -1 2 - 5 Gasoline 86290 -81-5 289 -220-8 2 - 5 Benzene 71-43-2 200-753-7 <0.1 This product consists primarily of ethanol (ethyl alcohol). Tanks should have secondary containment, be fire rated and resistant to impact. Dangerous Goods List (ADR, Chap. cooling liquids in refrigerators, oil-based electric heaters), outdoor use in close systems with minimal release (e.g. It characterizes the product with regard to the appropriate safety precautions. Properties of concern are calculated at four "levels" of certainty: The following properties of concern are calculated: The substance properties displayed in this section are derived from Harmonised classification and labelling (CLH) data, entries in the Candidate list of substances of very high concern for authorisation, the PBT assessment list, the ED assessment list, REACH registered dossier data and from notifications made under CLP. This is unique source of information on the chemicals manufactured and imported in Europe. Close Find out more on how we use cookies. Ethanol was first discovered as a by-product of fermenting alcohol, has been used in chemistry since the 1850s, and due to its versatility is now widely used in industry and homes around the world. The EC Inventory is a combination of three independent European lists of substances from the previous EU chemicals regulatory frameworks (EINECS, ELINCS and the NLP-list). Special precautions: None known. It is preferable to store ethanol in tanks above ground rather than below ground. But what is... read more, In chemistry, pure chemicals refer to substances that only contain one type of fundamental unit, like an atom or... read more, Brick acid is an extremely powerful cleaner for the building trade that, as the name suggests, removes tough debris... read more, Potassium iodide (KI) is a white crystalline solid that is formed by reacting elemental iodine (I) with potassium hydroxide... read more, When buying chemical products online, you will notice that the concentrations are either marked as v/v, w/w or w/v.... read more, Before we look at how ethanol is made, let’s explore what it is and what it’s used for. Ethanol is a flammable liquid. Can I Use Isopropyl Alcohol Instead of Denatured Alcohol? It applies the European Agreements on the international transport of dangerous goods by road (ADR) and inland waterways (ADN), and the Regulations concerning the international carriage of dangerous goods by rail (RID). Clean spills immediately. A prioritisation hierarchy means that data is taken from harmonised C&L data and regulatory lists first, then REACH registrations and finally from CLP notifications. Do not drink anything. If the substance was not covered by the EC Inventory, ECHA attributes a list number in the same format, starting with the numbers 6, 7, 8 or 9. The molecular formula identifies each type of element by its chemical symbol and identifies the number of atoms of each element found in one discrete molecule of the substance. Substances listed in the EINECS, ELINCS, or NLP inventories. was first discovered as a by-product of fermenting alcohol, has been used in chemistry since the 1850s, and due to its versatility is now widely. Ethanol is a strongly-smelling, volatile, flammable liquid – so yes, the short answer is that ethanol is hazardous! This substance is used in the following products: fuels, coating products, anti-freeze products, washing & cleaning products, biocides (e.g. When mixed with air the vapour is explosive, and can travel to the ignition point and flash back. Some data submitters indicate they consider this substance as Carcinogenic. Seek medical assistance if the irritation persists. It can spread along the ground and collect in compact areas such as tanks, and is a hazard both indoors and outdoors. The date of the last update corresponds to the publication date of the InfoCard and not necessarily to the date in which the update occurred in the source data. The vapour can catch fire at 13 °C and is easily ignited by heat or sparks. For some entries, the list includes functional classes, maximum and minimum limit values, and other restrictions. Material Safety Data Sheet, Misc. Ethanol and its vapour are highly flammable, so it’s important to know its flash points. Food Contact Regenerated Cellulose Directive - Authorised Substances, EU Ecolabels - Restrictions for Hazardous Substances/Mixtures, FCM and Articles Regulation, Annex I - Authorised Substances, ETHANOL (ETHYL ALCOHOL) or ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION), Inland Transport of Dangerous Goods Directive, Annex III - ADN, Inland Transport of Dangerous Goods Directive, Annex I - ADR, Inland Transport of Dangerous Goods Directive, Annex II - RID, ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION), CAD - Chemical Agents Directive, Art. If there is a substantial ethanol spill, make There are a number of reasons why ethanol is hazardous: Ethanol Is Flammable. Learn about side effects, drug interactions, dosages, warnings, and more. This directive requires employers to ensure proper signage is posted in areas where hazards cannot be avoided or reduced. These notifications can be provided by manufacturers, importers and downstream users. More information about CAS and the CAS registry can be found here. The purpose of the information provided under this section is to highlight the substance hazardousness in a readable format. The vapour can catch fire at 13 °C and is easily ignited by heat or sparks. The source of the information is mentioned in the introductory sentence of the hazard statements. Inhalation – get into fresh air as soon as possible and contact the emergency services for help. hydraulic liquids in automotive suspension, lubricants in motor oil and break fluids) and indoor use in close systems with minimal release (e.g. Substances indicated, in 2009, as being intended to be registered by at least one company in the EEA. Substances approved or for which approval is sought as Biocidal active substances. Contact with your eyes can cause immediate stinging pain, but may not cause a serious injury. If no EU harmonised classification and labelling exists and the substance was not registered under REACH, information derived from classification and labelling (C&L) notifications to ECHA under CLP Regulation is displayed under this section. Substances may have impurities and additives that lead to different classifications. The Hazard fields include special hazard alerts air and water reactions, fire hazards, health hazards, a reactivity profile, and ... ETHANOL reacts violently with acetyl chloride and acetyl bromide [Rose, (1961); Merck 11th ed., 1989]. This site is not fully supported in Internet Explorer 7 (and earlier versions). The Waste Framework Directive aims to protect the environment and human health from the generation and management of waste and to improve efficient use of resources. Be aware of location of fire extinguishers. When information is available in all sources, the first two are displayed as a priority. Eye contact – flush your eyes for at least 15 minutes and contact the emergency services. This database contains the ADR's Dangerous Goods List, as implemented by the EU's Directive 2008/68/EC. Impurities or additives: When a specific critical property is calculated from industry data and where the majority of data submitters have indicated that the property relates to cases containing impurities and/or additives, then the respective critical property icon is modified with an asterisk (*). A substance may have its use restricted to certain articles or products and therefore not all the examples may apply to the specific substance. If a substance is classified under multiple CLH entries, a link to the C&L Inventory is provided to allow users to view CLH information associated with the substance and no text is automatically generated for the InfoCard. Note that for readability purposes, only the pictograms, signal words and hazard statements referred in more than 5% of the notifications under CLP are displayed. Drugs A-Z Pill Identifier Supplements Symptom Checker Diseases Dictionary Media You should also ensure that any pipes, as well as the container, are not susceptible to corrosion by ethanol. Precautions for Loading, Unloading, Transport and Storage of Methanol Methanol requires that handlers pay particular attention to two specific hazards in order to avoid accidental release and ignition of methanol and methanol mixtures: 1.) This database contains substances that have been assigned hazard property (HP) waste codes 1-15, as defined in terms of the hazard class & category, hazard (H) statement, and/or concentration limits provided in Annex III of the Waste Framework Directive (2008/98/EC). Ethanol is highly inflammable and combustible so keep away from open flame, sparks and ignition sources. It applies the European Agreements on the international transport of dangerous goods by road (ADR) and inland waterways (ADN), and the Regulations concerning the international carriage of dangerous goods by rail (RID). Éthanol 96%, Ph.Eur., extra pur numéro d'article: P075 Version: 5.0 fr Remplace la version de: 27.01.2020 Version: (4) date d’établissement: 27.07.2015 Révision: 16.06.2020 France (fr) Page 1 / 17. This information is only displayed if the substance is well-defined, its identity is not claimed confidential and there is sufficient information available in ECHA’s databases for ECHA’s algorithms to generate a molecular structure. When heated until it burns, ethanol gives off acrid smoke and fumes. Other release to the environment of this substance is likely to occur from: outdoor use in long-life materials with low release rate (e.g. And ethanol is flammable. Furthermore, some substances can be found in an article, but with unlikely exposure (e.g. The annexes to this directive provide detailed information about the minimum requirements for all safety and health signs. Public (risk management) activities co-ordination table. Precautionary statements - describe recommended measures to minimise or prevent adverse effects resulting from exposure to a hazardous product or improper storage or handling of a hazardous product. While the harmonized list covers many hazardous substances, other ones not listed may also meet the classification criteria in accordance with the CLP. Ethanol is a toxic substance that when ingested by people in small amounts can have intoxicating effects similar to those of alcohol. ReAgent is one of the leading chemical suppliers in the UK. The Prior Informed Consent Regulation administers the import and export of certain hazardous chemicals and places obligations on companies who wish to export these chemicals to non-EU countries. Occupational exposure limit (OEL) values are derived within two legal frameworks that form an integral part of the EU’s mechanism for protecting the health of workers. 1-(3-nitrophenyl)ethanol | 5400-78-2 pricing, chemical properties, structure, CAS Number, Molecular Formula This list contains the substances and substance groups authorized by the EU in the manufacture of regenerated cellulose film intended to come into contact with foodstuffs. The ‘Substance identity’ section is calculated from substance identification information from all ECHA databases. If generated, an InChI string will also be generated and made available for searching. It even occurs naturally in certain things we consume. This substance can be found in complex articles, with no release intended: machinery, mechanical appliances, electrical/electronic products not covered by Waste Electrical and Electronic Equipment (WEEE) directive (e.g. flooring, furniture, toys, construction materials, curtains, foot-wear, leather products, paper and cardboard products, electronic equipment). Ethanol is a corrosive chemical and on an industrial level should be kept in stainless steel containers. ECHA maintains the C&L Inventory, but does not review or verify the accuracy of the information. Burn injury; smoke inhalation. IMDG UN3475 Ethanol and gasoline mixture 3 PG II No IATA UN3475 Ethanol and gasoline mixture 3 PG II No Transport in bulk (according to Annex II of MARPOL 73/78 and the IBC Code): Not applicable. Move containers from fire area if you can do so without risk. When mixed with air the vapour is explosive, and can travel to the ignition point and flash back. disinfectants, pest control products), finger paints, adhesives and sealants, leather treatment products, polishes and waxes, plant protection products, fillers, putties, plasters, modelling clay and lubricants and greases. The use information is displayed per substance life cycle stage (consumer use, in articles, by professional workers (widespread uses), in formulation or re-packing, at industrial sites or in manufacturing). 2(b)(i), Directive 98/24/EC on Protection of Workers from Chemical Agent-related Risks, 5 May 1998 (Table 3 of Annex VI to CLP, as amended), EU. The quality and correctness of the information submitted to ECHA remains the responsibility of the data submitter. A student wants to use a Bunsen burner to heat a test tube of ethanol. Ethanol is highly inflammable and combustible so keep away from open flame, sparks and ignition sources. It is preferable to store ethanol in tanks above ground rather than below ground. We do not recommend using any chemical without first consulting the Material Safety Data Sheet which can be obtained from the manufacturer and following the safety advice and precautions on the product label. 3 Effective date : 11.19.2014 Page 4 of 9 Ethanol, Lab Grade, 500mL Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com Special hazards arising from the substance or mixture: Please note: Precautionary measures and guidance on safe use concern the use and handling of the specific substance as such, not of the presence of the substance in other articles or mixtures. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners), indoor use in close systems with minimal release (e.g. Do not try and vomit as it can damage mucous membranes and organs. The ‘Properties of concern’ section shows ECHA-assigned graphical indicators for certain substance properties that are regarded as being of relevance or importance to human health and/or the environment based on the information provided to the Agency. The described Product category (i.e. Substances Authorized in Manufacture of Regenerated Cellulose Film for Use as FCM (Annex II), Directive 2007/42/EC, 30 June 2007, EU. If it is drunk in its pure form, it can be lethal or cause coma. In an industrial context it’s important to follow safety guidelines when handling ethanol. Ethanol, Lab Grade, 500mL Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com Special hazards arising from the substance or mixture: Combustion products may include carbon oxides or other toxic vapors.Dangerous fire hazard when exposed to heat, sparks and open flames. Compendium of Chemical Hazards: Ethanol Page 5 of 15 Incident Management Physicochemical Properties CAS number 64-17-5 Molecular weight 46.07 Formula C 2 H 6 O Common synonyms Ethyl alcohol, grain alcohol State at room temperature Clear, colourless liquid Volatility 59.3 mmHg at 25°C, volatile Specific gravity 0.8 (water = 1) Flammability Highly flammable The CAS number is the substance numerical identifier assigned by the Chemical Abstracts Service, a division of the American Chemical Society, to substances registered in the CAS registry database. This substance is registered under the REACH Regulation and is manufactured in and / or imported to the European Economic Area, at ≥ 1 000 000 per annum. Bondloc Hand Sanitiser Gel (Ethanol) Specific hazards Highly flammable liquid and vapour. The EC or list number is the primary substance identifier used by ECHA. : Ethanol is extremely flammable and poses a serious risk of fire, and thus burns to persons, when used in conjunction with alcohol burners at laminar flow benches. – get into fresh air as soon as possible and contact the emergency services for help. At least one company has indicated that the substance classification is affected by impurities or additives. 3.2, Table A), Directive 2008/68/EC, last amended by Regulation 2019/1243/EU, 25 July 2019, EU. Advice for firefighters: Inhalation of ethanol vapours can make you feel drowsy so do get out of the vapours quickly. HEALTH WARNINGS: Vapour is harmful on prolonged exposure or in high concentration. Protect against electrostatic charges. Also referred to as the Plastics Implementation Measure (PIM), this Regulation provides the Union List of monomers and other substances authorized in the manufacture of food contact plastics. inside a watch) or with very low concentrations considered not to pose risks to human health or the environment. Glycerol/Glycerine/Glycerin (General Use), sell ethanol in sizes ranging from 500ml to 2.5 litres, Removing Sticky Labels with Rubbing Alcohol. , so it’s important to know its flash points. This Directive establishes rules for the safe transport of dangerous goods between EU countries by road, rail, and waterway. This database contains the ADN's Dangerous Goods List, as implemented by the EU's Directive 2008/68/EC. When working with flammable liquids such as ethanol care should be taken to eliminate any fire hazards. release from fabrics, textiles during washing, removal of indoor paints) and indoor use in long-life materials with low release rate (e.g. We are based in Cheshire, England and have been established since 1977. Table 3 of Annex VI to CLP Regulation); and (2) the Candidate List of substances of very high concern (SVHC). However, substance notifications in the InfoCard are aggregated independently of the impurities and additives. The effects of ethanol on health are observed in those who consume excessive alcoholic beverages: nausea, vomiting, dizziness, even respiratory paralysis. 6(6), Reg. and precautions for firefighters In case of fire and/or explosion do not breathe fumes. Chemical Safety Data Guide, Bureau of National Affairs, 1985. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners), outdoor use in close systems with minimal release (e.g. Despite being common and having myriad uses, ethanol is a hazardous chemical and should be treated with care. – flush your eyes for at least 15 minutes and contact the emergency services. It is the responsibility of the substance manufacturers and importers to consult official publications, e.g. Label elements Signal word Warning Hazard statement Flammable liquid and vapor. Methanol is highly flammable and toxic. ETHANOL ABSOLUTE Pictogram Signal word Danger Hazard statements H225 Highly flammable liquid and vapour. This substance can be found in products with material based on: paper (e.g. EU. Ethanol may dissolve fiberglass resin, causing engine damage and possibly allow leakage of explosive gasoline. This substance is used in the following areas: scientific research and development and building & construction work. Precautionary statements P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. It can spread along the ground and collect in compact areas such as tanks, and is a hazard both indoors and outdoors. Non-Exhaustive List of Banned Substances, Directive 94/33/EC on Young People at Work, 20 August 1994, as amended by Dir 2014/27/EU, March 5, 2014 (Based on Table 3 of Annex VI to CLP, inter alia), EU. It does not represent a new labelling, classification or hazard statement, neither reflect other factors that affect the susceptibility of the effects described, such as duration of exposure or substance concentration (e.g. Hazards Of Ethanol. You Can Now Buy Pallet Quantities of Water Online, 11b – 13 Aston Fields Road, Whitehouse Industrial Estate, Runcorn, Cheshire, WA7 3DL. This substance has been found in the following regulatory activities (directly, or inheriting the regulatory context of a parent substance): This list represents a calculated inventory of substances based on the list of harmonized substances contained in Table 3 of Annex VI to the CLP Regulation (1272/2008/EC). to 29 CFR 1910.1200 App D 95% Ethanol Version number: GHS 1.0 Date of compilation: 2018-04-25 disodium tetraborate EC no. The Merck Index, 11. edition, 1989. May form explosive mixture with air at very high concentration. Guidance on safe use - recommendations by substance registrant on the proper use of the substance in various situations. While the harmonized list covers many hazardous substances, other ones not listed may also meet the classification criteria in accordance with the CLP. Additionally, the classification provided by companies to ECHA in REACH registrations identifies that this substance causes damage to organs, is toxic if swallowed, may cause cancer, is toxic in contact with skin, is toxic if inhaled, causes serious eye damage and causes skin irritation. 3.2, Table A), Directive 2008/68/EC, last amended by Regulation 2019/1243/EU, 25 July 2019, EU. Isopropyl alcohol and denatured alcohol both have a variety of applications in a range of industries. Substances for which an agreed set of classification and labelling data has been agreed at EU level by Member States. ’ section is calculated from substance identification information from all interested parties and to gather the widest possible of! An InChI string will also be generated and made available as soon possible! By heat or sparks if present, may not cause a burning sensation in InfoCard! Use a Bunsen burner to heat a test tube of ethanol is a dangerous chemical high.! 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A newer Version regulatory information safety, health, and waterway exclusively on starch- and sugar-based feedstocks please... Hazard assessment books, magazines, wallpaper ) be registered by at least one company in the,. And outdoor use in close systems with minimal release ( e.g of MSDS sheets vapour can fire. Companies which have been registered and can travel to the ignition point and flash back, and! Construction work according to 29CFR1910/1200 and GHS Rev information safety, health, its!